Atomically precise thiolate protected gold and more generally metal nanoclusters have
metal-core diameters of 1-1.8 nm, and the number and nature of the metal atoms and capping ligands are
clearly defined. Over the last years, synthetic and purification procedures have been implemented to such a
high level that many of them could be prepared and extensively studied. Important properties could be
assessed through careful studies of the nanoclusters' optical, magnetic, and electron-transfer behaviors.
This course will showcase the chemistry and physical chemistry of these nanosystems, starting from the
synthesis, purification, and main characterization techniques. Then, their magnetic, optical, photophysical,
and electrochemical behaviors will be described and analyzed. Finally, the course will cover applications
with a special focus on electro- and photo-catalysis.
Teachers: Flavio Maran, Sabrina Antonello, Sara Bonacchi, Alfonso Zoleo
Curriculum: Chemical Sciences
Duration: 24 hours
- Docente: Sabrina Antonello
- Docente: Sara Bonacchi
- Docente: Flavio Maran
- Docente: Alfonso Zoleo